
The Italian, ranked 21, had treatment at 3-0 down and decided to quit when Williams was leading 4-0 and 40-0.
Williams, who won last week's title in Madrid, will play either China's Li Na or Dominika Cibulkova of Slovakia in the last four.
Holder Maria Sharapova was due to play Venus Williams later on Friday while Wimbledon champion Petra Kvitova was scheduled to face Angelique Kerber of Germany.
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